Robert E. Mulvey

Research.com Recognitions

• 2001 - Fellow of the Royal Society of Edinburgh
• 1988 - Meldola Medal and Prize, Royal Society of Chemistry (UK)

Overview

Best Publications

• Deprotonative metalation using ate compounds: synergy, synthesis, and structure building

  Robert E. Mulvey;Florence Mongin;Masanobu Uchiyama;Yoshinori Kondo

  723
  Citations

• Meldola Medal Lecture. Ring-stacking and ring-laddering in organonitrogenlithium compounds: the development of concepts with wide applicability throughout lithium structural chemistry

  Robert E. Mulvey

  550
  Citations

• Modern Ate Chemistry: Applications of Synergic Mixed Alkali-Metal−Magnesium or −Zinc Reagents in Synthesis and Structure Building

  Robert E. Mulvey

  457
  Citations

• Avant-garde metalating agents: structural basis of alkali-metal-mediated metalation.

  Robert E. Mulvey

  444
  Citations

• Synthetically Important Alkali‐Metal Utility Amides: Lithium, Sodium, and Potassium Hexamethyldisilazides, Diisopropylamides, and Tetramethylpiperidides

  Robert E. Mulvey;Stuart D. Robertson

  258
  Citations

• s-Block metal inverse crowns: synthetic and structural synergism in mixed alkali metal–magnesium (or zinc) amide chemistry

  Robert E. Mulvey

  258
  Citations

• Deprotonierende Metallierungen mit 'at‐Verbindungen: Synergie, Synthese und Strukturaufbau

  Robert E. Mulvey;Florence Mongin;Masanobu Uchiyama;Yoshinori Kondo

  257
  Citations

• Synthetic and structural developments in hetero-s-block-metal chemistry: new ring-laddering, ring-stacking and other architectures

  Robert E. Mulvey

  257
  Citations

• Alkali-Metal-Mediated Synergistic Effects in Polar Main Group Organometallic Chemistry

  Stuart D. Robertson;Marina Uzelac;Robert E. Mulvey

  256
  Citations

• Alkali-metal mediation: diversity of applications in main-group organometallic chemistry

  Thomas X. Gentner;Robert E. Mulvey

  196
  Citations

• Directed ortho-meta′- and meta-meta′-dimetalations: A template base approach to deprotonation

  Antonio J. Martínez-Martínez;Alan R. Kennedy;Robert E. Mulvey;Charles T. O’Hara

  195
  Citations

• Synergic sedation of sensitive anions: alkali-mediated zincation of cyclic ethers and ethene

  Alan R. Kennedy;Jan Klett;Robert E. Mulvey;Dominic S. Wright

  179
  Citations

• Intermetallic Lithium−Magnesium Hexamethyldisilazide: Synthesis and Structure, Discovery of an Oxygen-Centered Variant, and a Reaction with Benzonitrile That Produces a Novel Amidinate Cage Compound with a Trigonal Bipyramidal Li4MgO Core

  Alan R. Kennedy;Robert E. Mulvey;René B. Rowlings

  166
  Citations

• A homologous series of regioselectively tetradeprotonated group 8 metallocenes: new inverse crown ring compounds synthesized via a mixed sodium-magnesium tris(diisopropylamide) synergic base.

  Prokopis C. Andrikopoulos;David R. Armstrong;William Clegg;Carly J. Gilfillan

  146
  Citations

• Sodium dialkyl-amidozincates : Alkyl or amido bases? An experimental and theoretical case study

  Prokopis C. Andrikopoulos;David R. Armstrong;Helen R. L. Barley;William Clegg

  143
  Citations

• Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

  Victoria A. Pollard;Samantha A. Orr;Ross McLellan;Alan R. Kennedy

  140
  Citations

• Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran

  Robert E Mulvey;Victoria Louise Blair;William Clegg;Alan Robert Kennedy

  140
  Citations

• Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases

  Pablo García-Álvarez;David V. Graham;Eva Hevia;Alan R. Kennedy

  136
  Citations

• Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences

  David R. Armstrong;Donald Barr;William Clegg;Susan M. Hodgson

  134
  Citations

• Alkali metal cation-pi interactions stabilized solely by [M{N(SiMe3)(2)}(3)](-) anions (M = Mg or Zn): The competing influence of alkali metal center dot center dot center dot C(Me) agostic interactions

  Glenn C. Forbes;Alan R. Kennedy;Robert E. Mulvey;Brett A. Roberts

  133
  Citations

• Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules

  David R. Armstrong;Alan R. Kennedy;Robert E. Mulvey;René B. Rowlings

  129
  Citations