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Chemistry

D-Index
97
Citations
29683
World Ranking
1489
National Ranking
570

Research.com Recognitions

  • 2014 - Fellow of the American Chemical Society
  • 1992 - Fellow of the American Association for the Advancement of Science (AAAS)

Overview

Kenneth D. Karlin is affiliated with Johns Hopkins University in the United States. Their research spans multiple fields, primarily focusing on Chemistry, Materials Science, and Biochemistry, Genetics and Molecular Biology. Within these disciplines, Karlin's work particularly concentrates on the subfields of Inorganic Chemistry, Materials Chemistry, Molecular Biology, Organic Chemistry, and Renewable Energy, Sustainability and the Environment.

The scientist's research topics extensively cover Metal-Catalyzed Oxygenation Mechanisms, Porphyrin and Phthalocyanine Chemistry, Metal Complexes Synthesis and Properties, Photosynthetic Processes and Mechanisms, Heme Oxygenase-1 and Carbon Monoxide, Crystallization and Solubility Studies, and X-ray Diffraction in Crystallography.

Karlin has published numerous papers, with a notable presence in several academic journals. Frequent publication venues include:

  • Journal of the American Chemical Society
  • Faraday Discussions
  • The Cambridge Structural Database
  • Inorganic Chemistry
  • Accounts of Chemical Research

Some of their recent papers are:

  • Heme-FeIII Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: FeIII-O2•- Complex H-Atom Abstraction Reactivity (2020), Journal of the American Chemical Society
  • Proton Relay in Iron Porphyrins for Hydrogen Evolution Reaction (2021), Inorganic Chemistry
  • Fenton-like Chemistry by a Copper(I) Complex and H2O2 Relevant to Enzyme Peroxygenase C-H Hydroxylation (2023), Journal of the American Chemical Society
  • A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity (2021), Journal of the American Chemical Society
  • End-On Copper(I) Superoxo and Cu(II) Peroxo and Hydroperoxo Complexes Generated by Cryoreduction/Annealing and Characterized by EPR/ENDOR Spectroscopy (2022), Journal of the American Chemical Society

Kenneth D. Karlin has collaborated frequently with other researchers in the field. Their frequent coauthors include:

  • Edward I. Solomon
  • Maxime A. Siegler
  • Mayukh Bhadra
  • Sanjib Panda
  • Pradip Kumar Hota

Awards granted to Karlin include the Fellow of the American Chemical Society in 2014 and the Fellow of the American Association for the Advancement of Science (AAAS) in 1992.

Best Publications

  • Metalloenzymes, structural motifs, and inorganic models

    Kenneth D. Karlin

  • Reversible reaction of O2 (and CO) with a copper(I) complex. X-ray structures of relevant mononuclear Cu(I) precursor adducts and the trans-(μ-1,2-peroxo)dicopper(II) product

    Zoltán Tyeklár;Zoltán Tyeklár;Richard R. Jacobson;Richard R. Jacobson;Ning Wei;Ning Wei;Narasappa Narasimha Murthy;Narasappa Narasimha Murthy

  • Bioinorganic Chemistry of Copper

    Kenneth D. Karlin;Zoltán Tyeklár

  • Nitric Oxide in Biological Denitrification: Fe/Cu Metalloenzyme and Metal Complex NOx Redox Chemistry

    Ian M. Wasser;Simon De Vries;Pierre MOëNNE-LOCCOZ;Imke Schröder

  • A Cu2-O2 Complex. Crystal Structure and Characterization of a Reversible Dioxygen Binding System

    Richard R. Jacobson;Zoltan. Tyeklar;Amjad. Farooq;Kenneth D. Karlin

  • Synthetic models for heme-copper oxidases.

    Eunsuk Kim;Eduardo E Chufán;Kaliappan Kamaraj;Kenneth D Karlin

  • Kinetics and Thermodynamics of Copper(I)/Dioxygen Interaction

    Kenneth D. Karlin;Susan Kaderli;Andreas D. Zuberbühler

  • Copper-mediated hydroxylation of an arene ― model system for the action of copper monooxygenases: structures of a binuclear Cu(I) complex and its oxygenated product

    Kenneth D. Karlin;Jon C. Hayes;Yilma Gultneh;Richard W. Cruse

  • Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell.

    Shunichi Fukuzumi;Shunichi Fukuzumi;Yusuke Yamada;Kenneth D. Karlin;Kenneth D. Karlin

  • Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity

    Lanying Q. Hatcher;Kenneth D. Karlin

  • Tetragonal vs. trigonal coordination in copper(II) complexes with tripod ligands: structures and properties of [Cu(C21H24N4)Cl]PF6 and [Cu(C18H18N4)Cl]PF6

    Kenneth D. Karlin;Jon C. Hayes;Shi Juen;John P. Hutchinson

  • Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: modeling copper-monooxygenase C-H hydroxylation.

    Debabrata Maiti;Dong-Heon Lee;Dong-Heon Lee;Katya Gaoutchenova;Christian Würtele

  • Binding and Activation of Molecular Oxygen by Copper Complexes

    Kenneth D. Karlin;Yilma Gultneh

  • Copper-dioxygen chemistry: a bioinorganic challenge

    Zoltan Tyeklar;Kenneth D. Karlin

  • Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO).

    Richard A Himes;Kenneth D Karlin

  • Copper(I) complexes, copper(I)/O(2) reactivity, and copper(II) complex adducts, with a series of tetradentate tripyridylalkylamine tripodal ligands.

    Markus Schatz;Michael Becker;Florian Thaler;Frank Hampel

  • Kinetics and thermodynamics of formation of copper-dioxygen adducts: oxygenation of mononuclear copper(I) complexes containing tripodal tetradentate ligands

    Kenneth D. Karlin;Ning Wei;Bernhard Jung;Susan Kaderli

  • Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function.

    Suzanne M. Adam;Gayan B. Wijeratne;Patrick J. Rogler;Daniel E. Diaz

  • Copper(I)−Dioxygen Reactivity of [(L)CuI]+ (L = Tris(2-pyridylmethyl)amine): Kinetic/Thermodynamic and Spectroscopic Studies Concerning the Formation of Cu−O2 and Cu2−O2 Adducts as a Function of Solvent Medium and 4-Pyridyl Ligand Substituent Variations

    Christiana Xin Zhang;Susan Kaderli;Miguel Costas;Eun-Il Kim

  • Peroxo-, Oxo-, and Hydroxo-Bridged Dicopper Complexes: Observation of Exogenous Hydrocarbon Substrate Oxidation

    Honorio V. Obias;Yin Lin;N. N. Murthy;Elna Pidcock

  • Dioxygen-copper reactivity. Reversible binding of O2 and CO to a phenoxo-bridged dicopper(I) complex

    Kenneth D. Karlin;Richard W. Cruse;Yilma Gultneh;Amjad Farooq

Frequent Co-Authors

Edward I. Solomon
Edward I. Solomon Stanford University
Jon Zubieta
Jon Zubieta Syracuse University
Shunichi Fukuzumi
Shunichi Fukuzumi Osaka University
Amy A. Sarjeant
Amy A. Sarjeant Bristol Myers Squibb
Maxime A. Siegler
Maxime A. Siegler Johns Hopkins University
Pierre Moënne-Loccoz
Pierre Moënne-Loccoz Oregon Health & Science University
Keith O. Hodgson
Keith O. Hodgson Stanford University
Ninian J. Blackburn
Ninian J. Blackburn Oregon Health & Science University
Britt Hedman
Britt Hedman SLAC National Accelerator Laboratory
Gerald J. Meyer
Gerald J. Meyer University of North Carolina at Chapel Hill

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