Gary E. Keck

Research.com Recognitions

• 1981 - Fellow of Alfred P. Sloan Foundation

Overview

Best Publications

• Catalytic asymmetric allylation of aldehydes

  Gary E. Keck;Kenneth H. Tarbet;Leo S. Geraci

  663
  Citations

• Proton-transfer steps in Steglich esterification: a very practical new method for macrolactonization

  Eugene P. Boden;Gary E. Keck

  603
  Citations

• Carbon-carbon bond formation via the reaction of trialkylallylstannanes with organic halides

  Gary E. Keck;John B. Yates

  349
  Citations

• One electron C-C bond forming reactions via allylstannanes: scope and limitations

  Gary E. Keck;Eric J. Enholm;John B. Yates;Michael R. Wiley

  343
  Citations

• PRONOUNCED SOLVENT AND CONCENTRATION EFFECTS IN AN ENANTIOSELECTIVE MUKAIYAMA ALDOL CONDENSATION USING BINOL-TITANIUM(IV) CATALYSTS

  Gary E. Keck;Dhileepkumar Krishnamurthy

  208
  Citations

• Catalytic asymmetric allylation reactions. 3. Extension to methallylstannane, comparison of procedures, and observation of a nonlinear effect

  Gary E. Keck;Dhileepkumar Krishnamurthy;Mark C. Grier

  192
  Citations

• Stereochemical consequences for the Lewis acid mediated additions of allyl and crotyltri-n-butylstannane to chiral β-hydroxyaldehyde derivatives

  Gary E. Keck;Duain E. Abbott

  190
  Citations

• USE OF SAMARIUM DIIODIDE AS AN ALTERNATIVE TO SODIUM/MERCURY AMALGAM IN THE JULIA-LYTHGOE OLEFINATION

  Gary E. Keck;Kenneth A. Savin;Michael A. Weglarz

  187
  Citations

• Catalytic Enantioselective Synthesis of Dihydropyrones via Formal Hetero Diels-Alder Reactions of "Danishefsky's Diene" with Aldehydes

  Gary E. Keck;Xiang Yi Li;Dhileepkumar Krishnamurthy

  186
  Citations

• Total Synthesis of Bryostatin 1

  Gary E. Keck;Yam B. Poudel;Thomas J. Cummins;Arnab Rudra

  180
  Citations

• Catalytic asymmetric allylation (CAA) reactions. II. A new enantioselective allylation procedure

  Gary E. Keck;Leo S. Geraci

  173
  Citations

• Stereocontrolled additions of allyltri-n-butyl-stannane to α-hydroxyaldehyde derivatives. A useful route to monoprotected erythro or threo diols.

  Gary E. Keck;Eugene P. Boden

  172
  Citations

• On the Origins of Stereoselectivity in "Chelation Controlled" Nucleophilic Additions to β-Alkoxy Aldehydes: Solution Structures of Lewis Acid Complexes via NMR Spectroscopy.

  G. E. Keck;S. Castellino

  158
  Citations

• Reductive cleavage of NO bonds in hydroxylamine and hydroxamic acid derivatives using SmI2/THF

  Gary E. Keck;Stanton F. McHardy;Travis T. Wager

  142
  Citations

• A versatile method for carbon-nitrogen bond formation via ene reactions of acylnitroso compounds

  Gary E. Keck;Robert R. Webb;John B. Yates

  141
  Citations

• Reductive cleavage of NO bonds in hydroxylamines and hydroxamic acid derivatives using samarium diiodide

  Gary E. Keck;Travis T. Wager;Stanton F. McHardy

  141
  Citations

• TOTAL SYNTHESIS OF (+)-7-DEOXYPANCRATISTATIN : A RADICAL CYCLIZATION APPROACH

  Gary E. Keck;Stanton F. McHardy;Jerry A. Murry

  140
  Citations

• Observations on the choice of Lewis acid and mode of addition for the Lewis acid mediated reaction of crotyltri-n-butylstannane with aldehydes: convenient and highly selective access to both erythro and threo products

  Gary E. Keck;Duain E. Abbott;Eugene P. Boden;Eric J. Enholm

  138
  Citations

• Homoallylamines from aldimines and allylstannanes

  Gary E. Keck;Eric J. Enholm

  133
  Citations

• Effects of olefin geometry on the stereochemistry of Lewis acid mediated additions of crotylstannanes to aldehydes

  Gary E. Keck;Kenneth A. Savin;Erik N.K. Cressman;Duane E. Abbott

  130
  Citations