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Alceo Macchioni

Alceo Macchioni

D-Index & Metrics

Chemistry

D-Index
59
Citations
12062
World Ranking
10162
National Ranking
310

Overview

Alceo Macchioni is affiliated with the University of Perugia in Italy. Their research spans several areas within materials science and chemistry, with a particular focus on materials chemistry and organic and inorganic chemistry. Macchioni's work also touches on renewable energy, sustainability, the environment, and electrical and electronic engineering.

The scientist's publication record includes contributions in several frequent venues, such as:

  • The Cambridge Structural Database
  • Inorganic Chemistry
  • European Journal of Inorganic Chemistry
  • ACS Catalysis
  • Chemistry - A European Journal

Macchioni's research topics encompass a range of specialized fields, including:

  • Crystallization and Solubility Studies
  • X-ray Diffraction in Crystallography
  • Organometallic Complex Synthesis and Catalysis
  • Electrocatalysts for Energy Conversion
  • Asymmetric Hydrogenation and Catalysis
  • Carbon dioxide utilization in catalysis
  • Organoboron and organosilicon chemistry

The scientist has worked collaboratively with a number of frequent co-authors including Cristiano Zuccaccia, Leonardo Tensi, Francesco Zaccaria, Luca Rocchigiani, and Gabriel Menendez Rodriguez.

Some recent publications by Alceo Macchioni include:

  • "Reactivity Trends of Lewis Acidic Sites in Methylaluminoxane and Some of Its Modifications," 2020, Inorganic Chemistry
  • "Extremely Fast NADH-Regeneration Using Phosphonic Acid as Hydride Source and Iridium-pyridine-2-sulfonamidate Catalysts," 2020, ACS Catalysis
  • "Salts of Lanthanide(III) Hexafluoroacetylacetonates [Ln = Sm(III), Eu(III) and Tb(III)] with Dipyridylammonium cations: Synthesis, characterization, photophysical properties and OLED fabrication," 2022, Dyes and Pigments
  • "Methylaluminoxane's Molecular Cousin: A Well-defined and "Complete" Al-Activator for Molecular Olefin Polymerization Catalysts," 2021, ACS Catalysis
  • "The Influence of the Ligand in the Iridium Mediated Electrocatalyic Water Oxidation," 2020, ACS Catalysis

Macchioni's research integrates structural chemistry techniques such as X-ray diffraction and crystallization studies, often applied to organometallic complexes and catalytic systems. Their work also addresses electrocatalysis related to energy conversion and explores sustainable catalysis pathways, including carbon dioxide utilization.

Best Publications

  • Determining accurate molecular sizes in solution through NMR diffusion spectroscopy

    Alceo Macchioni;Gianluca Ciancaleoni;Cristiano Zuccaccia;Daniele Zuccaccia

  • Simple and hydrolyzable compounds in virgin olive oil. 3. Spectroscopic characterizations of the secoiridoid derivatives.

    Gian Francesco Montedoro;Maurizio Servili;Maura Baldioli;Roberto Selvaggini

  • Ion pairing in transition-metal organometallic chemistry.

    Alceo Macchioni

  • Ultralarge Hyperpolarizability Twisted π-Electron System Electro-Optic Chromophores: Synthesis, Solid-State and Solution-Phase Structural Characteristics, Electronic Structures, Linear and Nonlinear Optical Properties, and Computational Studies

    Hu Kang;Antonio Facchetti;Hua Jiang;Elena Cariati

  • High‐performance liquid chromatography evaluation of phenols in olive fruit, virgin olive oil, vegetation waters, and pomace and 1D‐ and 2D‐nuclear magnetic resonance characterization

    Maurizio Servili;Maura Baldioli;Roberto Selvaggini;Enrico Miniati

  • An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2.

    Leah N. Appelhans;Daniele Zuccaccia;Anes Kovacevic;Anthony R. Chianese

  • NOE and PGSE NMR Spectroscopic Studies of Solution Structure and Aggregation in Metallocenium Ion-Pairs

    Cristiano Zuccaccia;Cristiano Zuccaccia;Nicholas G. Stahl;Alceo Macchioni;Ming Chou Chen

  • Iridium(III) molecular catalysts for water oxidation: the simpler the faster.

    Arianna Savini;Gianfranco Bellachioma;Gianluca Ciancaleoni;Cristiano Zuccaccia

  • Activity and degradation pathways of pentamethyl-cyclopentadienyl-iridium catalysts for water oxidation

    Arianna Savini;Paola Belanzoni;Gianfranco Bellachioma;Cristiano Zuccaccia

  • Exceptional Molecular Hyperpolarizabilities in Twisted π‐Electron System Chromophores

    Hu Kang;Antonio Facchetti;Peiwang Zhu;Hua Jiang

  • Ion pairing in cationic olefin-gold(I) complexes.

    Daniele Zuccaccia;Leonardo Belpassi;Francesco Tarantelli;Alceo Macchioni

  • An Accurate Methodology to Identify the Level of Aggregation in Solution by PGSE NMR Measurements: The Case of Half-Sandwich Diamino Ruthenium(II) Salts

    Daniele Zuccaccia and;Alceo Macchioni

  • Suppression of β-Hydride Chain Transfer in Nickel(II)-Catalyzed Ethylene Polymerization via Weak Fluorocarbon Ligand–Product Interactions

    Michael P. Weberski;Changle Chen;Massimiliano Delferro;Cristiano Zuccaccia

  • Synthesis, Ion Aggregation, Alkyl Bonding Modes, and Dynamics of 14-Electron Metallocenium Ion Pairs [(SBI)MCH2SiMe3+···X-] (M = Zr, Hf): Inner-Sphere (X = MeB(C6F5)3) versus Outer-Sphere (X = B(C6F5)4) Structures and the Implications for “Continuous” or “Intermittent” Alkene Polymerization Mechanisms

    Fuquan Song;Simon J. Lancaster;Roderick D. Cannon;Mark Schormann

  • Counterion effect on CO/styrene copolymerization catalyzed by cationic palladium(II) organometallic complexes: an interionic structural and dynamic investigation based on NMR spectroscopy

    Alceo Macchioni;Gianfranco Bellachioma;Giuseppe Cardaci;Monia Travaglia

  • Fate of pig sludge liquid fraction in calcareous soil : Agricultural and environmental implications

    P. L. Giusquiani;L. Concezzi;M. Businelli;A. Macchioni

  • Elucidation of the Solution Structures of Transition Metal Complex Ion Pairs by NOE NMR Experiments

    Alceo Macchioni

  • Probing the association of frustrated phosphine-borane Lewis pairs in solution by NMR spectroscopy.

    Luca Rocchigiani;Gianluca Ciancaleoni;Cristiano Zuccaccia;Alceo Macchioni

  • Intra- and Intermolecular NMR Studies on the Activation of Arylcyclometallated Hafnium Pyridyl-Amido Olefin Polymerization Precatalysts

    Cristiano Zuccaccia;Alceo Macchioni;Vincenzo Busico;Roberta Cipullo

  • A Phosphine Gold(I) π-Alkyne Complex: Tuning the Metal−Alkyne Bond Character and Counterion Position by the Choice of the Ancillary Ligand

    Daniele Zuccaccia;Leonardo Belpassi;Luca Rocchigiani;Francesco Tarantelli

Frequent Co-Authors

Cristiano Zuccaccia
Cristiano Zuccaccia University of Perugia
Vincenzo Busico
Vincenzo Busico University of Naples Federico II
Francesco Tarantelli
Francesco Tarantelli University of Perugia
Roberta Cipullo
Roberta Cipullo University of Naples Federico II
Peter H. M. Budzelaar
Peter H. M. Budzelaar University of Naples Federico II
Tobin J. Marks
Tobin J. Marks Northwestern University
Eric Clot
Eric Clot University of Montpellier
Renato Ugo
Renato Ugo University of Milan
Antonio Facchetti
Antonio Facchetti Northwestern University

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