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Chemistry

D-Index
60
Citations
14249
World Ranking
9618
National Ranking
321

Overview

Pablo Espinet is affiliated with the University of Valladolid in Spain and has a research focus primarily in the field of Materials Science. Their work spans multiple subfields including Materials Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Electronic, Optical and Magnetic Materials, and Pharmaceutical Science.

The main topics of Pablo Espinet's research activity encompass:

  • Crystallization and Solubility Studies
  • X-ray Diffraction in Crystallography
  • Catalytic Cross-Coupling Reactions
  • Crystallography and molecular interactions
  • Organometallic Complex Synthesis and Catalysis
  • Catalytic C-H Functionalization Methods
  • Fluorine in Organic Chemistry

Espinet has an extensive publication record, with frequent contributions to several scientific journals. The most common publication venues include:

  • The Cambridge Structural Database
  • Chemical Communications
  • Inorganic Chemistry
  • Journal of Materials Chemistry C
  • Organometallics

Their notable recent papers include:

  • Fluorinated vs Nonfluorinated PR2(biaryl) Ligands and Their [AuCl(L)] Complexes: Synthesis, X-ray Structures, and Computational Study of Weak Interactions. Bond, No Bond, and Beyond, 2020, published in Inorganic Chemistry
  • Easy wide scope access to luminescent fluorophosphoranes, 2021, published in Chemical Communications
  • Understanding the Use of Phosphine-(EWO) Ligands in Negishi Cross-Coupling: Experimental and Density Functional Theory Mechanistic Study, 2021, published in Organometallics
  • Striking Increase in Hole Mobility upon Metal Coordination to Triphenylene Schiff Base Semiconducting Multicolumnar Mesophases, 2020, published in Inorganic Chemistry
  • Ranking Ligands by Their Ability to Ease (C6F5)2NiIIL → Ni0L + (C6F5)2 Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands, 2020, published in Inorganic Chemistry

Espinet collaborates frequently with several researchers, including Marconi N. Peñas-Defrutos, Jaime Ponce-de-León, Camino Bartolomé, Andrea Vélez, and Sara Fernández-Moyano.

Best Publications

  • The Mechanisms of the Stille Reaction

    Pablo Espinet;Antonio M. Echavarren

  • Transition metal liquid crystals: advanced materials within the reach of the coordination chemist

    Pablo Espinet;Miguel A. Esteruelas;Luis A. Oro;José Luis Serrano

  • The Stille Reaction, 38 Years Later

    Carlos Cordovilla;Camino Bartolomé;Jesús Ma Martínez-Ilarduya;Pablo Espinet

  • Phosphine-pyridyl and related ligands in synthesis and catalysis

    Pablo Espinet;Katerina Soulantica

  • Unlikeliness of Pd-Free Gold(I)-Catalyzed Sonogashira Coupling Reactions

    Thorsten Lauterbach;Madeleine Livendahl;Antonio Rosellón;Pablo Espinet

  • Bimetallic catalysis using transition and Group 11 metals: an emerging tool for C-C coupling and other reactions.

    Mónica H. Pérez-Temprano;Juan A. Casares;Pablo Espinet

  • Mechanism of the Stille Reaction. 1. The Transmetalation Step. Coupling of R1I and R2SnBu3 Catalyzed by trans-[PdR1IL2] (R1 = C6Cl2F3; R2 = Vinyl, 4-Methoxyphenyl; L = AsPh3)

    Arturo L. Casado and;Pablo Espinet

  • ON THE CONFIGURATION RESULTING FROM OXIDATIVE ADDITION OF RX TO PD(PPH3)4 AND THE MECHANISM OF THE CIS-TO-TRANS ISOMERIZATION OF PDRX(PPH3)2 COMPLEXES (R = ARYL, X = HALIDE)

    Arturo L. Casado;Pablo Espinet

  • C-C reductive elimination in palladium complexes, and the role of coupling additives. A DFT study supported by experiment.

    Martín Pérez-Rodríguez;Ataualpa A. C. Braga;Max Garcia-Melchor;Mónica H. Pérez-Temprano

  • Efficient synthesis of chiral 1,1'-binaphthalenes by the asymmetric suzuki-miyaura reaction: dramatic synthetic improvement by simple purification of naphthylboronic acids.

    Miroslav Genov;Antonio Almorín;Pablo Espinet

  • Die Mechanismen der Stille‐Reaktion

    Pablo Espinet;Antonio M. Echavarren

  • A warning on the use of radical traps as a test for radical mechanisms: they react with palladium hydrido complexes.

    Ana C. Albéniz;Pablo Espinet;Raquel López-Fernández;Ayusman Sen

  • Synthesis and Catalytic Activity of Gold Chiral Nitrogen Acyclic Carbenes and Gold Hydrogen Bonded Heterocyclic Carbenes in Cyclopropanation of Vinyl Arenes and in Intramolecular Hydroalkoxylation of Allenes

    Camino Bartolomé;Domingo García-Cuadrado;Zoraida Ramiro;Pablo Espinet

  • Quantitative Evaluation of the Factors Contributing to the “Copper Effect” in the Stille Reaction

    Arturo L. Casado and;Pablo Espinet

  • Insights into the mechanism of the Negishi reaction: ZnRX versus ZnR2 reagents.

    Juan A. Casares;Pablo Espinet;Beatriz Fuentes;Gorka Salas

  • Nitrogen Acyclic Gold(I) Carbenes: Excellent and Easily Accessible Catalysts in Reactions of 1,6-Enynes

    Camino Bartolomé;Zoraida Ramiro;Domingo García-Cuadrado;Patricia Pérez-Galán

  • A critical analysis of the cyclic and open alternatives of the transmetalation step in the stille cross-coupling reaction.

    Ainara Nova;Gregori Ujaque;Feliu Maseras;and Agustí Lledós

  • A Novel Approach to Ferroelectric Liquid Crystals: the First Organotransition Metal Compound Displaying This Behavior

    Pablo Espinet;Jesús Etxebarría;Mercedes Marcos;Joaquina Pérez

  • Ferroelectric Behavior in Metal-Containing Liquid-Crystals - A Structure-Activity Study

    M. J. Baena;J. Barbera;P. Espinet;A. Ezcurra

  • Mesogenic behavior of silver thiolates with layered structure in the solid state: covalent soaps

    Maria J. Baena;Pablo Espinet;M. Carmen Lequerica;Anne Marie Levelut

Frequent Co-Authors

José Luis Serrano
José Luis Serrano Catalan Institution for Research and Advanced Studies
Rafael Usón
Rafael Usón Spanish National Research Council
Juan Forniés
Juan Forniés Universidad de Zaragoza
Peter M. Maitlis
Peter M. Maitlis University of Sheffield
Elena Lalinde
Elena Lalinde University of La Rioja
Peter G. Jones
Peter G. Jones Technische Universität Braunschweig
Agustí Lledós
Agustí Lledós Autonomous University of Barcelona
Yves Jeannin
Yves Jeannin Sorbonne University
Gregori Ujaque
Gregori Ujaque Autonomous University of Barcelona
George M. Sheldrick
George M. Sheldrick University of Göttingen

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