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Chemistry

D-Index
66
Citations
10608
World Ranking
7517
National Ranking
540

Overview

Shenglai Yao is affiliated with the Technical University of Berlin in Germany and has contributed extensively to the fields of Chemistry and Materials Science. Their research spans several subfields including Materials Chemistry, Organic Chemistry, Inorganic Chemistry, Physical and Theoretical Chemistry, and Electrical and Electronic Engineering.

Their work covers a range of topics such as:

  • Crystallization and Solubility Studies
  • X-ray Diffraction in Crystallography
  • Synthesis and characterization of novel inorganic/organometallic compounds
  • Organoboron and organosilicon chemistry
  • Organometallic Complex Synthesis and Catalysis
  • Coordination Chemistry and Organometallics
  • Crystallography and molecular interactions

Yao has published in various high-impact journals, with frequent publications in:

  • The Cambridge Structural Database
  • Angewandte Chemie International Edition
  • Angewandte Chemie
  • Journal of the American Chemical Society
  • Chemical Science

Selected recent papers include:

  • Redox Noninnocent Monoatomic Silicon(0) Complex ("Silylone"): Its One-Electron-Reduction Induces an Intramolecular One-Electron-Oxidation of Silicon(0) to Silicon(I), 2020, Journal of the American Chemical Society
  • Changing the Reactivity of Zero- and Mono-Valent Germanium with a Redox Non-Innocent Bis(silylenyl)carborane Ligand, 2021, Angewandte Chemie International Edition

Other notable recent papers co-authored by researchers associated with Yao include:

  • Where silylene-silicon centres matter in the activation of small molecules, 2020, Chemical Society Reviews
  • Facile Access to an Active γ-NiOOH Electrocatalyst for Durable Water Oxidation Derived From an Intermetallic Nickel Germanide Precursor, 2020, Angewandte Chemie International Edition
  • A bis(silylene)-stabilized diphosphorus compound and its reactivity as a monophosphorus anion transfer reagent, 2020, Nature Chemistry

Frequent collaborators in Yao's research network include:

  • Matthias Drieß
  • Arseni Kostenko
  • Marcel-Philip Luecke
  • Yun Xiong
  • Jun Zhu

Best Publications

  • Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

    Shenglai Yao;Yun Xiong;Matthias Driess

  • A new type of N-heterocyclic silylene with ambivalent reactivity.

    Matthias Driess;Shenglai Yao;Markus Brym;Christoph van Wüllen

  • A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom.

    Yun Xiong;Shenglai Yao;Shigeyoshi Inoue;Jan Dirk Epping

  • An isolable NHC-supported silanone.

    Yun Xiong;Shenglai Yao;Matthias Driess

  • A cyclic germadicarbene ("germylone") from germyliumylidene.

    Yun Xiong;Shenglai Yao;Gengwen Tan;Shigeyoshi Inoue

  • A Heterofulvene‐Like Germylene with a Betain Reactivity

    Matthias Driess;Shenglai Yao;Markus Brym;Christoph van Wüllen

  • From a Stable Silylene to a Mixed‐Valent Disiloxane and an Isolable Silaformamide–Borane Complex with Considerable Silicon–Oxygen Double‐Bond Character

    Shenglai Yao;Markus Brym;Christoph van Wüllen;Matthias Driess

  • Consecutive insertion of a silylene into the P4 tetrahedron: facile access to strained SiP4 and Si2P4 cage compounds.

    Yun Xiong;Shenglai Yao;Markus Brym;Matthias Driess

  • Facile Access to an Active γ-NiOOH Electrocatalyst for Durable Water Oxidation Derived From an Intermetallic Nickel Germanide Precursor.

    Prashanth W. Menezes;Shenglai Yao;Rodrigo Beltrán-Suito;J. Niklas Hausmann

  • Where silylene-silicon centres matter in the activation of small molecules.

    Changkai Shan;Shenglai Yao;Matthias Driess

  • Low-valent silicon cations with two-coordinate silicon and aromatic character.

    Matthias Driess;Shenglai Yao;Markus Brym;Christoph van Wüllen

  • From a Molecular 2Fe-2Se Precursor to a Highly Efficient Iron Diselenide Electrocatalyst for Overall Water Splitting.

    Chakadola Panda;Prashanth W. Menezes;Carsten Walter;Shenglai Yao

  • An Isolable Silanoic Ester by Oxygenation of a Stable Silylene

    Shenglai Yao;Yun Xiong;Markus Brym;Matthias Driess

  • Chemical Tricks To Stabilize Silanones and Their Heavier Homologues with EO Bonds (E=Si–Pb): From Elusive Species to Isolable Building Blocks

    Yun Xiong;Shenglai Yao;Matthias Driess

  • N‐Heterocyclic Carbene (NHC)‐Stabilized Silanechalcogenones: NHC→Si(R2)E (E=O, S, Se, Te)

    Shenglai Yao;Yun Xiong;Matthias Driess

  • From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature

    Yun Xiong;Shenglai Yao;Robert Müller;Martin Kaupp

  • Lessons from isolable nickel(I) precursor complexes for small molecule activation.

    Shenglai Yao;Matthias Driess

  • Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins.

    Yuwen Wang;Arseni Kostenko;Shenglai Yao;Matthias Driess

  • A “Side-on” Superoxonickel Complex [LNi(O2)] with a Square-Planar Tetracoordinate Nickel(II) Center and Its Conversion into [LNi(μ-OH)2NiL]†

    Shenglai Yao;Eckhard Bill;Carsten Milsmann;Karl Wieghardt

  • Activation of ammonia by a Si=O double bond and formation of a unique pair of sila-hemiaminal and silanoic amide tautomers.

    Yun Xiong;Shenglai Yao;Robert Müller;Martin Kaupp

Frequent Co-Authors

Matthias Driess
Matthias Driess Technical University of Berlin
Yun Xiong
Yun Xiong Technical University of Berlin
Shigeyoshi Inoue
Shigeyoshi Inoue Technical University of Munich
Eckhard Bill
Eckhard Bill Max Planck Society
Martin Kaupp
Martin Kaupp Technical University of Berlin
Peter Hildebrandt
Peter Hildebrandt Technical University of Berlin
Karsten Meyer
Karsten Meyer University of Erlangen-Nuremberg
Yitzhak Apeloig
Yitzhak Apeloig Technion – Israel Institute of Technology
Kallol Ray
Kallol Ray Humboldt-Universität zu Berlin
Michael Haumann
Michael Haumann Freie Universität Berlin

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