D-Index & Metrics Best Publications

D-Index & Metrics D-index (Discipline H-index) only includes papers and citation values for an examined discipline in contrast to General H-index which accounts for publications across all disciplines.

Discipline name D-index D-index (Discipline H-index) only includes papers and citation values for an examined discipline in contrast to General H-index which accounts for publications across all disciplines. Citations Publications World Ranking National Ranking
Chemistry D-index 53 Citations 7,479 123 World Ranking 9596 National Ranking 2765

Overview

What is he best known for?

The fields of study he is best known for:

  • Organic chemistry
  • Catalysis
  • Alkene

Kinetic isotope effect, Computational chemistry, Kinetic energy, Photochemistry and Organic chemistry are his primary areas of study. Kinetic isotope effect is connected with Cycloaddition, Ene reaction, Chemical physics, Selectivity and Cyclohexenone in his research. Daniel A. Singleton has researched Computational chemistry in several fields, including Sublimation, Regioselectivity and Mechanism.

His research investigates the connection between Regioselectivity and topics such as Transition state theory that intersect with issues in Alkene. Daniel A. Singleton focuses mostly in the field of Mechanism, narrowing it down to topics relating to Alcohol and, in certain cases, Molecule. His work carried out in the field of Photochemistry brings together such families of science as Iridium, Catalysis, Stereoisomerism, Ligand and Borylation.

His most cited work include:

  • A Case Study of the Mechanism of Alcohol-Mediated Morita Baylis–Hillman Reactions. The Importance of Experimental Observations (236 citations)
  • High-Precision Simultaneous Determination of Multiple Small Kinetic Isotope Effects at Natural Abundance (209 citations)
  • Mechanism of Ene Reactions of Singlet Oxygen. A Two-Step No-Intermediate Mechanism (163 citations)

What are the main themes of his work throughout his whole career to date?

His primary areas of study are Organic chemistry, Kinetic isotope effect, Diels alder, Medicinal chemistry and Photochemistry. His study of Kinetic isotope effect brings together topics like Kinetic energy, Computational chemistry, Intramolecular force, Cycloaddition and Chemical physics. In his work, Reaction rate constant is strongly intertwined with Reaction mechanism, which is a subfield of Computational chemistry.

His Diels alder study combines topics from a wide range of disciplines, such as Boron, Regioselectivity, Aliphatic compound, Bicyclic molecule and Stereoselectivity. The concepts of his Medicinal chemistry study are interwoven with issues in Lewis acids and bases and Silylation. Daniel A. Singleton combines subjects such as Ene reaction, Transition state and Stereoisomerism with his study of Photochemistry.

He most often published in these fields:

  • Organic chemistry (38.93%)
  • Kinetic isotope effect (34.23%)
  • Diels alder (22.15%)

What were the highlights of his more recent work (between 2008-2021)?

  • Kinetic isotope effect (34.23%)
  • Photochemistry (19.46%)
  • Selectivity (11.41%)

In recent papers he was focusing on the following fields of study:

Daniel A. Singleton mainly focuses on Kinetic isotope effect, Photochemistry, Selectivity, Molecule and Computational chemistry. Kinetic isotope effect combines with fields such as Kinetic energy, Intramolecular force, Chemical physics, Physical chemistry and Decarboxylation in his work. The various areas that Daniel A. Singleton examines in his Photochemistry study include Solvent, Stereoisomerism, Ligand, Borylation and Iridium.

His Molecule study combines topics in areas such as Ion, Inorganic chemistry and Cycloaddition, Catalysis. His study in the field of Potential of mean force also crosses realms of Spinosyn A. His Hydroboration study which covers Work that intersects with Organic chemistry.

Between 2008 and 2021, his most popular works were:

  • A Case Study of the Mechanism of Alcohol-Mediated Morita Baylis–Hillman Reactions. The Importance of Experimental Observations (236 citations)
  • Dynamics and the failure of transition state theory in alkene hydroboration. (97 citations)
  • Outer-Sphere Direction in Iridium C-H Borylation (97 citations)

In his most recent research, the most cited papers focused on:

  • Organic chemistry
  • Catalysis
  • Alkene

His primary scientific interests are in Computational chemistry, Molecule, Cycloaddition, Kinetic isotope effect and Selectivity. His Computational chemistry research is multidisciplinary, incorporating perspectives in Ab initio quantum chemistry methods, Regioselectivity, Markovnikov's rule, Boranes and Alkene. His Molecule research is multidisciplinary, relying on both Triethylamine, Stereochemistry, Bipyridine, Catalysis and Combinatorial chemistry.

He interconnects Bond formation, Adduct and Potential energy surface in the investigation of issues within Cycloaddition. Along with Kinetic isotope effect, other disciplines of study including Intramolecular force, Alcohol, Mechanism, Physical chemistry and Morita therapy are integrated into his research. Daniel A. Singleton combines subjects such as Molecular dynamics, Diels–Alder reaction, Methyl vinyl ketone, Transition state theory and Transition state with his study of Selectivity.

This overview was generated by a machine learning system which analysed the scientist’s body of work. If you have any feedback, you can contact us here.

Best Publications

High-Precision Simultaneous Determination of Multiple Small Kinetic Isotope Effects at Natural Abundance

Daniel A. Singleton;Allen A. Thomas.
Journal of the American Chemical Society (1995)

421 Citations

A Case Study of the Mechanism of Alcohol-Mediated Morita Baylis–Hillman Reactions. The Importance of Experimental Observations

R. Erik Plata;Daniel A. Singleton.
Journal of the American Chemical Society (2015)

384 Citations

Experimental and Theoretical Kinetic Isotope Effects for Asymmetric Dihydroxylation. Evidence Supporting a Rate-Limiting “(3 + 2)” Cycloaddition

A. J. DelMonte;J. Haller;K. N. Houk;K. B. Sharpless.
Journal of the American Chemical Society (1997)

324 Citations

Mechanism of Ene Reactions of Singlet Oxygen. A Two-Step No-Intermediate Mechanism

Daniel A Singleton;Chao Hang;Michael J Szymanski;Matthew P Meyer.
Journal of the American Chemical Society (2003)

274 Citations

Synchronous or Asynchronous? An “Experimental” Transition State from a Direct Comparison of Experimental and Theoretical Kinetic Isotope Effects for a Diels−Alder Reaction

Brett R. Beno;K. N. Houk;Daniel A. Singleton.
Journal of the American Chemical Society (1996)

194 Citations

Experimental Geometry of the Epoxidation Transition State

Daniel A. Singleton;Steven R. Merrigan;Jian Liu;K. N. Houk.
Journal of the American Chemical Society (1997)

184 Citations

Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations.

Daniel T. Nowlan;Timothy M. Gregg;Huw M. L. Davies;Daniel A. Singleton.
Journal of the American Chemical Society (2003)

179 Citations

Phenomenon of optical self-purification of chiral non-racemic compounds

Vadim A. Soloshonok;Hisanori Ueki;Manabu Yasumoto;Shekar Mekala.
Journal of the American Chemical Society (2007)

178 Citations

Dynamic effects on the periselectivity, rate, isotope effects, and mechanism of cycloadditions of ketenes with cyclopentadiene.

Bryson R. Ussing;Chao Hang;Daniel A. Singleton.
Journal of the American Chemical Society (2006)

173 Citations

Dynamics and the failure of transition state theory in alkene hydroboration.

Yatsandra Oyola;Daniel A. Singleton.
Journal of the American Chemical Society (2009)

167 Citations

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