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Chemistry

D-Index
81
Citations
21015
World Ranking
3298
National Ranking
1089

Overview

Patrick J. Walsh is affiliated with the University of Pennsylvania in the United States. Their primary field of study is Chemistry, with a strong focus on Organic Chemistry, supported by significant work in Inorganic Chemistry, Molecular Biology, Materials Chemistry, and Atmospheric Science.

The research topics that dominate the scientist's work include:

  • Catalytic C-H Functionalization Methods
  • Radical Photochemical Reactions
  • Catalytic Cross-Coupling Reactions
  • Sulfur-Based Synthesis Techniques
  • Asymmetric Hydrogenation and Catalysis
  • Synthesis and Catalytic Reactions
  • Chemical Synthesis and Analysis

Key publications by Patrick J. Walsh cover a range of recent cutting-edge research:

  • Photocatalytic C-H activation and the subtle role of chlorine radical complexation in reactivity, 2021, Science
  • Nickel/Photoredox-Catalyzed Asymmetric Reductive Cross-Coupling of Racemic α-Chloro Esters with Aryl Iodides, 2020, Angewandte Chemie International Edition
  • Migratory functionalization of unactivated alkyl bromides for construction of all-carbon quaternary centers via transposed tert-C-radicals, 2020, Nature Communications
  • Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate, 2020, Proceedings of the National Academy of Sciences
  • Catalytic enantioselective reductive domino alkyl arylation of acrylates via nickel/photoredox catalysis, 2021, Nature Communications

Frequent publication venues provide insight into their dissemination channels, including:

  • Chemical Science
  • Organic Letters
  • Angewandte Chemie International Edition
  • Angewandte Chemie
  • Organic Chemistry Frontiers

Collaborations play an important role in their research output, with frequent coauthors such as:

  • Jianyou Mao
  • Xiaodong Yang
  • Haoqiang Zhao
  • Hongbin Zhang
  • Jie Li

Best Publications

  • Inside Cover: Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Umpolung 1,4-Addition of Aryl Iodides to Enals (Angew. Chem. Int. Ed. 1/2020)

    Wenjun Yang;Bo Ling;Bowen Hu;Haolin Yin

  • Stoichiometric and catalytic hydroamination of alkynes and allene by zirconium bisamides Cp2Zr(NHR)2

    Patrick J. Walsh;Anne M. Baranger;Robert G. Bergman

  • Generation, alkyne cycloaddition, arene carbon-hydrogen activation, nitrogen-hydrogen activation and dative ligand trapping reactions of the first monomeric imidozirconocene (Cp2Zr:NR) complexes

    Patrick J. Walsh;Frederick J. Hollander;Robert G. Bergman

  • A Green Chemistry Approach to Asymmetric Catalysis: Solvent-Free and Highly Concentrated Reactions

    Patrick J. Walsh;Hongmei Li;Cecilia Anaya de Parrodi

  • Fundamentals Of Asymmetric Catalysis

    Patrick J. Walsh;Marisa Kowzlowski

  • Monomeric and dimeric zirconocene imido compounds: synthesis, structure, and reactivity

    Patrick J. Walsh;Frederick J. Hollander;Robert G. Bergman

  • Contribution of fish to the marine inorganic carbon cycle.

    R. W. Wilson;F. J. Millero;J. R. Taylor;P. J. Walsh;P. J. Walsh

  • Variable regiochemistry in the stoichiometric and catalytic hydroamination of alkynes by imidozirconium complexes caused by an unusual dependence of the rate law on alkyne structure and temperature

    Anne M. Baranger;Patrick J. Walsh;Robert G. Bergman

  • Photocatalytic C–H activation and the subtle role of chlorine radical complexation in reactivity

    Qiaomu Yang;Yu-Heng Wang;Yusen Qiao;Michael Gau

  • The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis

    Nicholas A. Piro;Jerome R. Robinson;Patrick J. Walsh;Eric J. Schelter

  • Insight into the mechanism of the asymmetric addition of alkyl groups to aldehydes catalyzed by titanium-BINOLate species.

    Jaume Balsells;Timothy J. Davis;Patrick Carroll;Patrick J. Walsh

  • Use of achiral and meso ligands to convey asymmetry in enantioselective catalysis

    Patrick J. Walsh;and Alice E. Lurain;Jaume Balsells

  • Palladium-catalyzed C(sp3)-H arylation of diarylmethanes at room temperature: synthesis of triarylmethanes via deprotonative-cross-coupling processes.

    Jiadi Zhang;Ana Bellomo;Andrea D. Creamer;Spencer D. Dreher

  • Innentitelbild: Synergistic N‑Heterocyclic Carbene/Palladium‑Catalyzed Umpolung 1,4‑Addition of Aryl Iodides to Enals (Angew. Chem. 1/2020)

    Wenjun Yang;Bo Ling;Bowen Hu;Haolin Yin

  • A general, highly enantioselective method for the synthesis of D and L alpha-amino acids and allylic amines.

    Young K. Chen;and Alice E. Lurain;Patrick J. Walsh

  • Cobalt–Bisoxazoline-Catalyzed Asymmetric Kumada Cross-Coupling of Racemic α-Bromo Esters with Aryl Grignard Reagents

    Jianyou Mao;Feipeng Liu;Min Wang;Lin Wu

  • A practical catalytic asymmetric addition of alkyl groups to ketones.

    Celina Garcia;Lynne K. Larochelle;Patrick J. Walsh

  • A Mechanistic Study of the Cycloaddition-Cycloreversion Reactions of Zirconium-Imido Complex Cp2Zr(N-t-Bu)(THF) with Organic Imines and Organic Azides

    Karen E. Meyer;Patrick J. Walsh;Robert G. Bergman

  • Titanium-catalyzed enantioselective additions of alkyl groups to aldehydes: mechanistic studies and new concepts in asymmetric catalysis.

    Patrick J. Walsh

  • Synthesis and Crystal Structures of Bis(sulfonamido) Titanium Bis(alkoxide) Complexes: Mechanistic Implications in the Bis(sulfonamide) Catalyzed Asymmetric Addition of Dialkylzinc Reagents to Aldehydes

    Suzy Pritchett;David H. Woodmansee;Peter Gantzel;Patrick J. Walsh

  • Catalytic asymmetric vinylation of ketones.

    Hongmei Li;Patrick J Walsh

  • Nickel/Photoredox‐Catalyzed Asymmetric Reductive Cross‐Coupling of Racemic α‐Chloro Esters with Aryl Iodides

    Haixing Guan;Qianwen Zhang;Patrick J. Walsh;Jianyou Mao

  • Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Umpolung 1,4-Addition of Aryl Iodides to Enals

    Wenjun Yang;Bo Ling;Bowen Hu;Haolin Yin

Frequent Co-Authors

Patrick J. Carroll
Patrick J. Carroll University of Pennsylvania
Eric J. Schelter
Eric J. Schelter University of Pennsylvania
Robert G. Bergman
Robert G. Bergman University of California, Berkeley
Miquel A. Pericàs
Miquel A. Pericàs University of Barcelona
Marsha I. Lester
Marsha I. Lester University of Pennsylvania
Per-Ola Norrby
Per-Ola Norrby AstraZeneca (Sweden)
Marisa C. Kozlowski
Marisa C. Kozlowski University of Pennsylvania
Zhenfeng Xi
Zhenfeng Xi Peking University
Stephen J. Klippenstein
Stephen J. Klippenstein Argonne National Laboratory
David L. Osborn
David L. Osborn Sandia National Laboratories

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