Gernot Boche

Overview

Best Publications

• The Structure of Lithium Compounds of Sulfones, Sulfoximides, Sulfoxides, Thioethers and 1,3-Dithianes, Nitriles, Nitro Compounds and Hydrazones

  Gernot Boche

  439
  Citations

• The electrophilic nature of carbenoids, nitrenoids, and oxenoids.

  Gernot Boche;John C. W. Lohrenz

  412
  Citations

• Metallophilic interactions in closed-shell copper(I) compounds--a theoretical study.

  Holger L. Hermann;Gernot Boche;Peter Schwerdtfeger

  268
  Citations

• Zur Struktur der Lithiumverbindungen von Sulfonen, Sulfoximiden, Sulfoxiden, Thioethern und 1,3‐Dithianen, Nitrilen, Nitroverbindungen und Hydrazonen

  Gernot Boche

  205
  Citations

• Generation of Enantiomerically Enriched Lithium Indenides by Means of (–)‐Sparteine: Structure, Stereoselective Substitution, and Solvent Effects

  Inga Hoppe;Michael Marsch;Klaus Harms;Gernot Boche

  147
  Citations

• The Crystal Structures of a Lower Order and a “Higher Order” Cyanocuprate: [tBuCu(CN)Li(OEt2)2]∞ and [tBuCutBu{Li(thf)(pmdeta)}2CN]

  Gernot Boche;Ferdinand Bosold;Michael Marsch;Klaus Harms

  144
  Citations

• The relation between ion pair structures and reactivities of lithium cuprates

  Michael John;Carsten Auel;Christoph Behrens;Michael Marsch

  143
  Citations

• η1-C6H5CH2Li•THF•TMEDA, Kristallstruktur eines Benzyllithium•THF•TMEDA-Komplexes mit einem pyramidalen Benzyl-C-Atom

  Wolfgang Zarges;Michael Marsch;Klaus Harms;Gernot Boche

  134
  Citations

• Crystal and electronic structure of stable nitrenium ions. A comparison with structurally related carbenes

  Gernot Boche;Phil Andrews;Klaus Harms;Michael Marsch

  127
  Citations

• [α‐(Dimethylamino)benzyllithium–Diethyl Ether]2, (S)‐α‐(Methylpivaloylamino)benzyllithium – (–)‐Sparteine, and [3‐Iodo‐2‐lithio‐1‐methylindole – 2 Tetrahydrofuran]2: Crystal Structure Investigations of α‐Lithiated Amines

  Gernot Boche;Michael Marsch;Jürgen Harbach;Klaus Harms

  118
  Citations

• The Equilibrium Between 2-Lithium-Oxazole(-Thiazole, -Imidazole) Derivatives and Their Acyclic Isomers – A Structural Investigation†

  Christoff Hilf;Ferdinand Bosold;Klaus Harms;Michael Marsch

  116
  Citations

• Röntgenstrukturuntersuchung von α‐(Trimethylsilyl)benzyllithium·Tetramethylendiamin [C6H5CH(SiMe3)Li·TMEDA] und α‐(Phenylthio)‐benzyllithium·3 Tetrahydrofuran [C6H5CH(SPh)Li·(THF)3] – zwei zentral‐chirale Benzyllithium‐Verbindungen

  Wolfgang Zarges;Michael Marsch;Klaus Harms;Gernot Frenking

  113
  Citations

• η1‐(1S, 2E)‐1‐(N,N‐diisopropylcarbamoyloxy)‐3‐trimethylsilylallyllithium( ? )‐Sparteine: Structure of a Chiral, Carbamoyloxy‐substituted Allyllithium Compound

  Michael Marsch;Klaus Harms;Oliver Zschage;Dieter Hoppe

  108
  Citations

• [((η2-tert-Butylperoxo)titanatrane)2· 3 Dichloromethane]: X-ray Crystal Structure and Oxidation Reactions

  Gernot Boche;Konrad Möbus;Klaus Harms;Michael Marsch

  107
  Citations

• [(α-Cyanobenzyllithium·Tetramethylethylenediamine)2·Benzene]: X-Ray Structure Analysis of an α-Nitrile "Carbanion"

  G. Boche;M. Marsch;K. Harms

  106
  Citations

• 1,1′-Bis(N,N-dimethylamino)ferrocene,1,1′-bis(N,N-dimethylamino) cobaltocenium hexafluorophosphate and 1,1′-bis(N,N-dimethylamino)titanocene dichloride. Crystal structure of 1,1′-bis(N,N-dimethylamino)titanocene dichloride

  Klaus-Peter Stahl;Gernot Boche;Werner Massa

  106
  Citations

• [nBuLi · LiOtBu]4, Solid‐State Structure of an n‐Butyllithium–Lithium tert‐Butoxide Complex

  Michael Marsch;Klaus Harms;Lubomir Lochmann;Gernot Boche

  102
  Citations

• α-Oxygen-Substituted Organolithium Compounds and Their Carbenoid Nature: Calculations of the Configurational Stability and of LiCH2OH Model Structures, Crystal Structure of Diphenyl(trimethylsilyloxy)methyllithium · 3 THF, and the Stereochemistry of the (Reverse) Brook Rearrangement

  Gernot Boche;Achim Opel;Michael Marsch;Klaus Harms

  102
  Citations

• α‐Oxygen‐Substituted Organolithium Compounds and their Carbenoid Nature: Reactions with RLi and Other Nucleophiles, Experimental and IGLO‐Calculated 13C‐NMR Shifts of the Carbenoid C Atom

  Gernot Boche;Ferdinand Bosold;John C. W. Lohrenz;Achim Opel

  97
  Citations

• X-Ray Structure Determination of [α-(Phenylsulfonyl)benzyllithium-Tetramethylethylenediamine]2: Chirality of an α-Sulfonyl “Carbanion”†‡

  Gernot Boche;Michael Marsch;Klaus Harms;George M. Sheldrick

  95
  Citations