His primary areas of study are Catalysis, Photochemistry, Ligand, Cobalt and Organic chemistry. The Catalysis study combines topics in areas such as Combinatorial chemistry, Inorganic chemistry, Hydride and Moiety. His studies deal with areas such as Palladium, Redox, Carbene, Radical and Nitrene as well as Photochemistry.
The study incorporates disciplines such as Polymerization and Polymer chemistry in addition to Carbene. His Radical research includes elements of Cyclopropanation, Medicinal chemistry and Porphyrin. His Ligand research is multidisciplinary, relying on both Amination, Crystallography, Intramolecular force, Stereochemistry and Azide.
Bas de Bruin spends much of his time researching Catalysis, Ligand, Photochemistry, Medicinal chemistry and Polymer chemistry. His Catalysis research is multidisciplinary, incorporating elements of Combinatorial chemistry and Cobalt. His work in Ligand tackles topics such as Reactivity which are related to areas like Organometallic chemistry.
He works mostly in the field of Photochemistry, limiting it down to concerns involving Rhodium and, occasionally, Pyridine and Reaction mechanism. In his work, Amination is strongly intertwined with Azide, which is a subfield of Medicinal chemistry. Bas de Bruin interconnects Supramolecular chemistry and Homogeneous catalysis in the investigation of issues within Polymer chemistry.
His scientific interests lie mostly in Catalysis, Polymer chemistry, Ligand, Medicinal chemistry and Radical. His Catalysis study incorporates themes from Combinatorial chemistry and Cobalt. His biological study spans a wide range of topics, including Styrene, Lewis acids and bases and Porphyrin.
His Ligand research incorporates themes from Nickel, Ruthenium, Steric effects, Moiety and Redox. His work carried out in the field of Medicinal chemistry brings together such families of science as Rhodium, Dimer, Catalytic cycle, Azide and Aryl. The Radical study combines topics in areas such as Photochemistry, Frustrated Lewis pair, Carbene and Nitrene.
Catalysis, Nitrene, Radical, Cobalt and Reactivity are his primary areas of study. He combines subjects such as Iodide and Medicinal chemistry with his study of Catalysis. Bas de Bruin has included themes like Ligand, Amidine, Combinatorial chemistry, Curtius rearrangement and Azide in his Nitrene study.
His Radical research integrates issues from Photochemistry and Frustrated Lewis pair, Lewis acids and bases. His Intramolecular force research extends to the thematically linked field of Photochemistry. His Cobalt research includes themes of Tetraphenylporphyrin, Polymer chemistry, Homogeneous catalysis and Carbene.
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Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions
Volodymyr Lyaskovskyy;Bas de Bruin.
ACS Catalysis (2012)
Transition metal catalysis in confined spaces
Stefan H. A. M. Leenders;Rafael Gramage-Doria;Bas de Bruin;Joost N. H. Reek.
Chemical Society Reviews (2015)
Molecular and electronic structures of bis(pyridine-2,6-diimine)metal complexes [ML2](PF6)n (n = 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn).
Bas de Bruin;Eckhard Bill;Eberhard Bothe;and Thomas Weyhermüller.
Inorganic Chemistry (2000)
Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates
Volodymyr Lyaskovskyy;Alma I. Olivos Suarez;Hongjian Lu;Huiling Jiang.
Journal of the American Chemical Society (2011)
‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation
Wojciech I. Dzik;Xue Xu;X. Peter Zhang;Joost N. H. Reek.
Journal of the American Chemical Society (2010)
Synthesis of functional ‘polyolefins’: state of the art and remaining challenges
Nicole M. G. Franssen;Joost N. H. Reek;Bas de Bruin.
Chemical Society Reviews (2013)
Ligands that Store and Release Electrons during Catalysis
Wojciech I. Dzik;Jarl Ivar van der Vlugt;Joost N. H. Reek;Bas de Bruin.
Angewandte Chemie (2011)
Hydrogenation of carboxylic acids with a homogeneous cobalt catalyst
Ties J Korstanje;Jarl Ivar van der Vlugt;Cornelis J Elsevier;Bas de Bruin.
Science (2015)
Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation
Hongjian Lu;Wojciech I. Dzik;Xue Xu;Lukasz Wojtas.
Journal of the American Chemical Society (2011)
Complexes with Nitrogen‐Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic Applications
Alma I. Olivos Suarez;Volodymyr Lyaskovskyy;Joost N. H. Reek;Jarl Ivar van der Vlugt.
Angewandte Chemie (2013)
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