World's Best Scientists 2026 revealed!

D-Index & Metrics

Chemistry

D-Index
78
Citations
46260
World Ranking
3719
National Ranking
212

Research.com Recognitions

  • 1987 - Corday–Morgan Prize, Royal Society of Chemistry (UK)
  • 1982 - Meldola Medal and Prize, Royal Society of Chemistry (UK)

Overview

What is he best known for?

The fields of study he is best known for:

  • Organic chemistry
  • Catalysis
  • Alkene

His scientific interests lie mostly in Stereochemistry, Ligand, Medicinal chemistry, Crystallography and Crystal structure. A. Guy Orpen works mostly in the field of Stereochemistry, limiting it down to topics relating to X-ray crystallography and, in certain cases, Inorganic compound. His biological study spans a wide range of topics, including Chelation, Computational chemistry, Steric effects and Nuclear magnetic resonance spectroscopy.

His study in Medicinal chemistry is interdisciplinary in nature, drawing from both Platinum, Catalysis, Metallacycle, Reactivity and Aryl. The various areas that A. Guy Orpen examines in his Crystallography study include Hydrogen, Metal and Hydrogen bond. His studies deal with areas such as Molecule and Alkyl as well as Crystal structure.

His most cited work include:

  • Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds (5822 citations)
  • Mechanochemistry: opportunities for new and cleaner synthesis (1407 citations)
  • Supplement. Tables of bond lengths determined by X-ray and neutron diffraction. Part 2. Organometallic compounds and co-ordination complexes of the d- and f-block metals (874 citations)

What are the main themes of his work throughout his whole career to date?

The scientist’s investigation covers issues in Stereochemistry, Crystal structure, Crystallography, Medicinal chemistry and Ligand. While the research belongs to areas of Stereochemistry, he spends his time largely on the problem of Protonation, intersecting his research to questions surrounding Hydride. His work in Crystal structure tackles topics such as X-ray crystallography which are related to areas like Triphenylphosphine.

His studies in Crystallography integrate themes in fields like Metal and Hydrogen bond. He interconnects Rhodium, Catalysis, Carbene, Photochemistry and Reactivity in the investigation of issues within Medicinal chemistry. He has researched Ligand in several fields, including Chelation, Steric effects, Nuclear magnetic resonance spectroscopy and Tetrahydrofuran.

He most often published in these fields:

  • Stereochemistry (53.24%)
  • Crystal structure (46.53%)
  • Crystallography (41.44%)

What were the highlights of his more recent work (between 2005-2017)?

  • Stereochemistry (53.24%)
  • Medicinal chemistry (35.19%)
  • Ligand (28.47%)

In recent papers he was focusing on the following fields of study:

Stereochemistry, Medicinal chemistry, Ligand, Crystallography and Crystal structure are his primary areas of study. A. Guy Orpen combines subjects such as Diphosphines, Phosphine, Catalysis and Rhodium with his study of Stereochemistry. His Medicinal chemistry research is multidisciplinary, incorporating elements of Palladium, Inorganic chemistry, Photochemistry, Coordination complex and Selectivity.

His research integrates issues of Chelation, Octahedron, Computational chemistry and Ring in his study of Ligand. The concepts of his Crystallography study are interwoven with issues in Ion, Molecule, Hydrogen bond and Metal. In his work, Diastereomer is strongly intertwined with Deprotonation, which is a subfield of Crystal structure.

Between 2005 and 2017, his most popular works were:

  • Mechanochemistry: opportunities for new and cleaner synthesis (1407 citations)
  • Building ligand knowledge bases for organometallic chemistry: Computational description of phosphorus(III)-donor ligands and the metal–phosphorus bond (133 citations)
  • Solid state interconversions of coordination networks and hydrogen-bonded salts (124 citations)

In his most recent research, the most cited papers focused on:

  • Organic chemistry
  • Catalysis
  • Alkene

A. Guy Orpen mostly deals with Ligand, Stereochemistry, Medicinal chemistry, Catalysis and Denticity. The Ligand study combines topics in areas such as Computational chemistry, Metal and Steric effects. His work deals with themes such as Crystallography, Scorpionate ligand, Crystal structure, Redox and Phosphine, which intersect with Stereochemistry.

A. Guy Orpen conducts interdisciplinary study in the fields of Crystallography and Ligand cone angle through his works. A. Guy Orpen has included themes like Palladium, Inorganic chemistry, Cobalt, Paramagnetism and Coordination complex in his Medicinal chemistry study. The study incorporates disciplines such as Chelation, Asymmetric hydrogenation and Bridging ligand in addition to Denticity.

Best Publications

  • Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds

    Frank H. Allen;Olga Kennard;David G. Watson;Lee Brammer

  • A chemically functionalizable nanoporous material (Cu3(TMA)2(H2O)3)n

    Unknown

  • Mechanochemistry: opportunities for new and cleaner synthesis

    Stuart L. James;Christopher J. Adams;Carsten Bolm;Dario Braga

  • Supplement. Tables of bond lengths determined by X-ray and neutron diffraction. Part 2. Organometallic compounds and co-ordination complexes of the d- and f-block metals

    A. Guy Orpen;Lee Brammer;Frank H. Allen;Olga Kennard

  • Retrieval of Crystallographically-Derived Molecular Geometry Information

    Ian J. Bruno;Jason C. Cole;Magnus Kessler;Jie Luo

  • Metal-bound chlorine often accepts hydrogen bonds

    Gabriel Aullón;Dena Bellamy;A. Guy Orpen;Lee Brammer

  • Bis(diisopropylamino)carbene

    Roger W. Alder;Paul R. Allen;Martin Murray;A. Guy Orpen

  • Indirect location of hydride ligands in metal cluster complexes

    A. Guy Orpen

  • β-Diiminato Complexes of VIII and TiIII – Formation and Structure of Stable Paramagnetic Dialkylmetal Compounds

    Peter H. M. Budzelaar;A. Bart van Oort;A. Guy Orpen

  • Innovation in crystal engineering

    Dario Braga;Gautam R. Desiraju;Joel S. Miller;A. Guy Orpen

  • Water-soluble tris(hydroxymethyl)phosphine complexes with nickel, palladium, and platinum. Crystal structure of [Pd{P(CH2OH)3}4].cntdot.CH3

    James W. Ellis;Karl N. Harrison;Peter A. T. Hoye;A. Guy Orpen

  • Typical interatomic distances: organic compounds

    F. H. Allen;D. G. Watson;L. Brammer;A. G. Orpen

  • Building ligand knowledge bases for organometallic chemistry: Computational description of phosphorus(III)-donor ligands and the metal–phosphorus bond

    Natalie Fey;A. Guy Orpen;Jeremy N. Harvey

  • Structural systematics: the role of P-A .sigma.* orbitals in metal-phosphorus .pi.-bonding in redox-related pairs of M-PA3 complexes (A = R, Ar, OR; R = alkyl)

    A. Guy Orpen;Neil G. Connelly

  • Biarylphosphonites: a class of monodentate phosphorus(III) ligands that outperform their chelating analogues in asymmetric hydrogenation catalysis

    Carmen Claver;Elena Fernandez;Amy Gillon;Katie Heslop

  • Lewis-base-free cationic zirconocene complexes containing an alkenyl ligand

    Andrew D. Horton;A. Guy. Orpen

  • Nickel Ethylene Polymerization Catalysts Based on Phosphorus Ligands

    Neil A. Cooley;and Simon M. Green;Duncan F. Wass;Katie Heslop

  • Ni(CO)4 and Fe(CO)5: molecular structures in the solid state

    D Braga;F Grepioni;AG Orpen

  • Expansion of the Ligand Knowledge Base for Monodentate P-Donor Ligands (LKB-P)†

    Jesús Jover;Natalie Fey;Jeremy N. Harvey;Guy C. Lloyd-Jones

  • Solid state interconversions of coordination networks and hydrogen-bonded salts

    Chris J Adams;HM Colquhoun;PC Crawford;M Lusi

  • SECONDARY BONDING AS A POTENTIAL DESIGN ELEMENT FOR CRYSTAL ENGINEERING

    Jonathan Starbuck;Nicholas C. Norman;A. Guy Orpen

Frequent Co-Authors

Nicholas C. Norman
Nicholas C. Norman University of Bristol
Ian D. Williams
Ian D. Williams Hong Kong University of Science and Technology
Lee Brammer
Lee Brammer University of Sheffield
Juan Forniés
Juan Forniés Universidad de Zaragoza
Mark Crocker
Mark Crocker University of Kentucky
Todd B. Marder
Todd B. Marder University of Würzburg
Duncan F. Wass
Duncan F. Wass Cardiff University
William Clegg
William Clegg Newcastle University
Antonio Martín
Antonio Martín University of Zaragoza

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