Tamio Hayashi

Research.com Recognitions

• 2026 - Research.com Chemistry in Taiwan Leader Award
• 2025 - Research.com Chemistry in Taiwan Leader Award
• 2007 - Ryoji Noyori Prize, Society of Synthetic Organic Chemistry

Overview

Best Publications

• Rhodium-catalyzed asymmetric 1,4-addition and its related asymmetric reactions

  Tamio Hayashi;Kaori Yamasaki

  1978
  Citations

• Catalytic asymmetric aldol reaction: reaction of aldehydes with isocyanoacetate catalyzed by a chiral ferrocenylphosphine-gold(I) complex

  Yoshihiko. Ito;Masaya. Sawamura;Tamio. Hayashi

  1017
  Citations

• Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II): an effective catalyst for cross-coupling of secondary and primary alkyl Grignard and alkylzinc reagents with organic halides

  Tamio Hayashi;Mitsuo Konishi;Yuji Kobori;Makoto Kumada

  1016
  Citations

• Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones

  Yoshiaki Takaya;and Masamichi Ogasawara;Tamio Hayashi;Masaaki Sakai and

  902
  Citations

• Catalytic Cycle of Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids. Arylrhodium, Oxa-π-allylrhodium, and Hydroxorhodium Intermediates

  Tamio Hayashi;Makoto Takahashi;Yoshiaki Takaya;Masamichi Ogasawara

  771
  Citations

• Chiral monodentate phosphine ligand MOP for transition-metal-catalyzed asymmetric reactions.

  Tamio Hayashi

  648
  Citations

• Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine–Transition Metal Complexes. I. Preparation of Chiral Ferrocenylphosphines

  Tamio Hayashi;Takaya Mise;Motoo Fukushima;Masahiro Kagotani

  625
  Citations

• A chiral chelating diene as a new type of chiral ligand for transition metal catalysts: its preparation and use for the rhodium-catalyzed asymmetric 1,4-addition.

  Tamio Hayashi;Kazuhito Ueyama;Norihito Tokunaga;Kazuhiro Yoshida

  610
  Citations

• C2-Symmetric Bicyclo[2.2.2]octadienes as Chiral Ligands: Their High Performance in Rhodium-Catalyzed Asymmetric Arylation of N-Tosylarylimines

  Norihito Tokunaga;Yusuke Otomaru;Kazuhiro Okamoto;Kazuhito Ueyama

  560
  Citations

• tert-Butoxide-mediated arylation of benzene with aryl halides in the presence of a catalytic 1,10-phenanthroline derivative.

  Eiji Shirakawa;Ken-ichi Itoh;Tomohiro Higashino;Tamio Hayashi

  532
  Citations

• Asymmetric synthesis catalyzed by chiral ferrocenylphosphine - transition-metal complexes. 8. Palladium-catalyzed asymmetric allylic amination

  Tamio Hayashi;Akihiro Yamamoto;Yoshihiko Ito;Eriko Nishioka

  453
  Citations

• Catalytic asymmetric arylation of 2,3-dihydrofuran with aryl triflates

  Fumiyuki Ozawa;Akihiko Kubo;Tamio Hayashi

  446
  Citations

• Catalytic asymmetric synthesis of optically active 2-alkanols via hydrosilylation of 1-alkenes with a chiral monophosphine-palladium catalyst

  Yasuhiro Uozumi;Tamio Hayashi

  425
  Citations

• Rhodium-Catalyzed Hydroarylation of Alkynes with Arylboronic Acids: 1,4-Shift of Rhodium from 2-Aryl-1-alkenylrhodium to 2-Alkenylarylrhodium Intermediate

  Tamio Hayashi;Kazuya Inoue;Nobukazu Taniguchi;Masamichi Ogasawara

  425
  Citations

• Iron-catalyzed Grignard cross-coupling with alkyl halides possessing beta-hydrogens.

  Takashi Nagano;Tamio Hayashi

  392
  Citations

• Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition-metal complexes. 6. Practical asymmetric synthesis of 1,1'-binaphthyls via asymmetric cross-coupling with a chiral [(alkoxyalkyl)ferrocenyl]monophosphine/nickel catalyst

  Tamio. Hayashi;Keiichi. Hayashizaki;Takao. Kiyoi;Yoshihiko. Ito

  385
  Citations

• Synthesis of optically active 2-(diarylphosphino)-1,1'-binaphthyls, efficient chiral monodentate phosphine ligands

  Yasuhiro Uozumi;Asako Tanahashi;Sang Yong Lee;Tamio Hayashi

  384
  Citations

• Rhodium-Catalyzed Asymmetric Addition of Aryl- and Alkenylboronic Acids to Isatins

  Ryo Shintani;Mitsunori Inoue;Tamio Hayashi

  348
  Citations

• Palladium-catalyzed asymmetric arylation of 2,3-dihydrofuran with phenyl triflate. A novel asymmetric catalysis involving a kinetic resolution process

  Fumiyuki Ozawa;Akihiko Kubo;Yonetatsu Matsumoto;Tamio Hayashi

  343
  Citations

• Modification of optically active ferrocenylphosphine ligands for palladium-catalyzed asymmetric allylic alkylation

  Tamio Hayashi;Akihiro Yamamoto;Toshiya Hagihara;Yoshihiko Ito

  327
  Citations

• Synthesis of All-Carbon Quaternary Stereocenters

  R. Shintani;Y. Tsutsumi;M. Nagaosa;T. Nishimura

  0
  Citations