Hideo Nagashima

Overview

Best Publications

• Chemoselective hydrogenation of nitroarenes with carbon nanofiber-supported platinum and palladium nanoparticles.

  Mikihiro Takasaki;Yukihiro Motoyama;Kenji Higashi;Seong Ho Yoon

  343
  Citations

• Hydrosilane Reduction of Tertiary Carboxamides by Iron Carbonyl Catalysts

  Yusuke Sunada;Hiroko Kawakami;Tsuyoshi Imaoka;Yukihiro Motoyama

  336
  Citations

• Practical access to amines by platinum-catalyzed reduction of carboxamides with hydrosilanes: synergy of dual Si-H groups leads to high efficiency and selectivity.

  Shiori Hanada;Emi Tsutsumi;Yukihiro Motoyama;Hideo Nagashima

  294
  Citations

• Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides.

  Daisuke Noda;Yusuke Sunada;Takuji Hatakeyama;Masaharu Nakamura

  249
  Citations

• Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes.

  Daisuke Noda;Atsushi Tahara;Yusuke Sunada;Hideo Nagashima

  234
  Citations

• A triruthenium carbonyl cluster bearing a bridging acenaphthylene ligand: an efficient catalyst for reduction of esters, carboxylic acids, and amides by trialkylsilanes.

  Kouki Matsubara;Takafumi Iura;Tomoyuki Maki;Hideo Nagashima

  230
  Citations

• Self-encapsulation of homogeneous catalyst species into polymer gel leading to a facile and efficient separation system of amine products in the Ru-catalyzed reduction of carboxamides with polymethylhydrosiloxane (PMHS)

  Yukihiro Motoyama;Kaoru Mitsui;Toshiki Ishida;Hideo Nagashima

  230
  Citations

• Highly efficient synthesis of aldenamines from carboxamides by iridium-catalyzed silane-reduction/dehydration under mild conditions

  Yukihiro Motoyama;Masaharu Aoki;Naoki Takaoka;Ryuta Aoto

  224
  Citations

• The ruthenium-catalyzed reduction and reductive N-alkylation of secondary amides with hydrosilanes: practical synthesis of secondary and tertiary amines by judicious choice of hydrosilanes.

  Shiori Hanada;Toshiki Ishida;Yukihiro Motoyama;Hideo Nagashima

  188
  Citations

• Transition metal-catalyzed radical cyclizations: a low-temperature process for the cyclization of N-protected N-allyltrichloroacetamides to trichlorinated .gamma.-lactams and application to the stereoselective preparation of .beta.,.gamma.-disubstituted .gamma.-lactams

  Hideo Nagashima;Nobuyasu Ozaki;Masayuki Ishii;Koji Seki

  184
  Citations

• C60Pdn: the first organometallic polymer of buckminsterfullerene

  Hideo Nagashima;Akihito Nakaoka;Yahachi Saito;Masanao Kato

  179
  Citations

• Palladium-catalyzed oxidative coupling of aromatic compounds with olefins using t-butyl perbenzoate as a hydrogen accepter

  Jiro Tsuji;Hideo Nagashima

  151
  Citations

• Dual Si–H effects in platinum-catalyzed silane reduction of carboxamides leading to a practical synthetic process of tertiary-amines involving self-encapsulation of the catalyst species into the insoluble silicone resin formed

  Shiori Hanada;Yukihiro Motoyama;Hideo Nagashima

  140
  Citations

• Chemistry of coordinatively unsaturated organoruthenium amidinates as entry to homogeneous catalysis

  Hideo Nagashima;Hideo Kondo;Taizo Hayashida;Yoshitaka Yamaguchi

  140
  Citations

• Bis(1-3:5-6-η-cyclooctadienyl)ruthenium: Preparation, NMR spectroscopy, and isomerization to (η6-1,3,5-cyclooctatriene)(1-2:5-6-η-1,5-cyclooctadiene)ruthenium via the activation of a CH bond

  Kenji Itoh;Hideo Nagashima;Toshiyuki Ohshima;Noriaki Oshima

  138
  Citations

• Transition metal catalyzed radical cyclization: new preparative route to .gamma.-lactams from allylic alcohols via the [3.3]-sigmatropic rearrangement of allylic trichloroacetimidates and the subsequent ruthenium-catalyzed cyclization of N-allyltrichloroacetamides

  Hideo Nagashima;Hidetoshi Wakamatsu;Nobuyasu Ozaki;Tsutomu Ishii

  136
  Citations

• Catalysis in polysiloxane gels: platinum-catalyzed hydrosilylation of polymethylhydrosiloxane leading to reusable catalysts for reduction of nitroarenes.

  Yukihiro Motoyama;Kazuyuki Kamo;Hideo Nagashima

  135
  Citations

• RHODIUM-CATALYZED SILYLFORMYLATION OF ACETYLENIC BONDS : ITS SCOPE AND MECHANISTIC CONSIDERATIONS

  Isamu Matsuda;Yukimasa Fukuta;Toru Tsuchihashi;Hideo Nagashima

  113
  Citations

• Transition-metal-catalyzed radical cyclization: copper-catalyzed cyclization of allyl trichloroacetates to trichlorinated .gamma.-lactones

  Hideo Nagashima;Koji Seki;Nobuyasu Ozaki;Hidetoshi Wakamatsu

  111
  Citations

• Oxidative addition of allylic halides to ruthenium(II) compounds. Preparation, reactions, and x-ray crystallographic structure of ruthenium(IV)-allyl complexes

  Hideo Nagashima;Katsunori Mukai;Yusuke Shiota;Keitaro Yamaguchi

  111
  Citations

• A Novel Approach to α-Silylmethylene-β-lactams via Rh-catalyzed Silylcarbonylation of Propargylamine Derivatives

  Isamu Matsuda;Jun Sakakibara;Hideo Nagashima

  110
  Citations