Kin-ya Akiba

Overview

Best Publications

• Syntheses and structures of hypervalent pentacoordinate carbon and boron compounds bearing an anthracene skeleton--elucidation of hypervalent interaction based on X-ray analysis and DFT calculation.

  Makoto Yamashita;Yohsuke Yamamoto;Kin-Ya Akiba;Daisuke Hashizume

  206
  Citations

• Synthesis of 1,4-Dithiafulvenes and 1,4-Dithiafulvalenes by Carbonyl Olefination Using 2-Dimethoxyphosphinyl-1,3-benzodithiole

  Kin-ya Akiba;Kiyofumi Ishikawa;Naoki Inamoto

  202
  Citations

• Synthesis and Isolation of Stable Hypervalent Carbon Compound (10-C-5) Bearing a 1,8-Dimethoxyanthracene Ligand

  Kin-ya Akiba;Makoto Yamashita;Yohsuke Yamamoto;Shigeru Nagase

  134
  Citations

• A grignard-type addition of allyl unit to aldehydes by using bismuth and bismuth salt

  Makoto Wada;Hidenori Ohki;Kin-ya Akiba

  129
  Citations

• Experimental Investigation on Edge Inversion at Trivalent Bismuth and Antimony: Great Acceleration by Intra- and Intermolecular Nucleophilic Coordination

  Yohsuke Yamamoto;Xiang Chen;Satoshi Kojima;Keisuke Ohdoi

  118
  Citations

• Synthesis and structure of 16 pi octaalkyltetraphenylporphyrins.

  Yohsuke Yamamoto;Akihiro Yamamoto;Shin-ya Furuta;Masanori Horie

  108
  Citations

• Regioselective synthesis of 4-alkylpyridines via 1,4-dihydropyridine derivatives from pyridine

  Kin-ya Akiba;Yuji Iseki;Makoto Wada

  100
  Citations

• Metallic bismuth mediated allylation of aldehydes to homoallylic alcohols

  Makoto Wada;Kin-ya Akiba

  96
  Citations

• Tandem reactions in 4-siloxy-1-benzopyrylium salts : introduction of substituents and cyclohexene and cyclopentane annulation in chromones

  Yong Gyun Lee;Kenji Ishimaru;Hideharu Iwasaki;Katsuo Ohkata

  95
  Citations

• Characteristic reactions and properties of C-apical O-equatorial (O-cis) spirophosphoranes: effect of the sigma(P)(-)(O) orbital in the equatorial plane and isolation of a hexacoordinate oxaphosphetane as an intermediate of the Wittig type reaction of 10-P-5 phosphoranes.

  Shiro Matsukawa;Satoshi Kojima;Kazumasa Kajiyama;Yohsuke Yamamoto

  91
  Citations

• FIRST CHARACTERIZATION OF A 10-P-5 SPIROPHOSPHORANE WITH AN APICAL CARBON-EQUATORIAL OXYGEN RING. KINETIC STUDIES ON PSEUDOROTATION OF STEREOISOMERS

  Satoshi Kojima;Kazumasa Kajiyama;Masaaki Nakamoto;Kin-ya Akiba

  91
  Citations

• Synthesis and structure of a hexacoordinate carbon compound.

  Torahiko Yamaguchi;Yohsuke Yamamoto;Daisuke Kinoshita;Kin-ya Akiba

  88
  Citations

• A Method for Determining the Difference in Relative Apicophilicity of Carbon‐Containing Substituents of 10‐P‐5 Phosphoranes

  Shiro Matsukawa;Kazumasa Kajiyama;Satoshi Kojima;Shin-ya Furuta

  87
  Citations

• Synthesis and Characterization of Stable Hypervalent Carbon Compounds (10-C-5) Bearing a 2,6-Bis(p-substituted phenyloxymethyl)benzene Ligand

  Kin-Ya Akiba;Yuji Moriyama;Mitsuhiro Mizozoe;Hideki Inohara

  86
  Citations

• Regioselective synthesis of 4-(2-oxoalkyl)pyridines via 1,4-dihydro-pyridine derivatives using silyl enol ethers and pyridinium salts

  Kin-ya Akiba;Yoshihiro Nishihara;Makoto Wada

  85
  Citations

• Synthesis and chemical behaviors of 12-substituted dibenz[c,f][1,5]azastibocine and dibenz[c,f][1,5]azabismocine derivatives: evidences of 10-Pn-4 type hypervalent interaction

  Katsuo Ohkata;Shin Takemoto;Masako Ohnishi;Kin-ya Akiba

  83
  Citations

• Synthesis, Reactions, and Electronic Properties of 16 π-Electron Octaisobutyltetraphenylporphyrin

  Yohsuke Yamamoto;Yusuke Hirata;Megumi Kodama;Torahiko Yamaguchi

  80
  Citations

• A convenient method for the regioselective synthesis of 4-alkyl(aryl)pyridines using pyridinium salts.

  Kin-ya Akiba;Makoto Wada

  78
  Citations

• Carbon-carbon bond formation with bismuth salt: a chemoselective Grignard-type addition of allyl unit to aldehydes

  Makoto Wada;Hidenori Ohki;Kin-ya Akiba

  77
  Citations

• Bismuth trichloride as a new efficient catalyst in the aldol reaction

  Hidenori Ohki;Makoto Wada;Kin-ya Akiba

  76
  Citations

• Synthesis and crystal structure of intramolecularly coordinated organobismuth compounds and edge inversion at trivalent bismuth

  Yohsuke Yamamoto;Xiang Chen;Kinya Akiba

  75
  Citations